Because the Stones' first Big Hits compilation had been released in separate formats, with the Aftermath-era material appearing only on its UK edition, the American edition of Big Hits Vol. 2 included hit singles from the Aftermath period.
The British track listing included the more obscure "You Better Move On", from The Rolling Stones' self-titled 1964 debut EP and "Sittin' on a Fence", an Aftermath outtake originally released in 1967 on the US compiled Flowers album. In addition to those songs, many tracks, notably single-only releases, were collected for the first time on a UK Rolling Stones album: "Let's Spend the Night Together", "Ruby Tuesday", "We Love You", "Dandelion", and "Honky Tonk Women".
The name of the album is a play on a line from the KJV translation of 1 Corinthians 13: "For now we see through a glass, darkly, but then face to face..."
The LP was packaged in an eight-sided die-cut gatefold sleeve, featuring an epitaph for Jones: "When this you see, remember me and bear me in your mind. Let all the world say what they may, speak of me as you find.